Adjust oven rack to the middle low position and preheat to 350°F.
Dissolve the espresso powder into the vanilla extract in a very small bowl. Set aside.
15 ml vanilla extract, 1/2 tsp espresso powder
Combine the cake flour, powdered sugar and cocoa, sift two times; set aside.
95 g cake flour, 60 g powdered sugar, 30 g cocoa powder
Combine egg whites and sugar in the bowl of a stand mixer fitted with the whisk attachment. Mix on low to loosen, about 1 minute, then Increase to medium-low and whip 3 minutes; the whites will be dense and dark.
540 g egg whites, 300 g granulated sugar
With the mixer still running, add cream of tartar and salt. Immediately increase to medium and whip 3 minutes more; the meringue will be thin but foamy. Increase to medium-high and continue whipping until the meringue is glossy white and holds a medium firm peak.
2 tsp cream of tartar, 1 g salt
Add the espresso vanilla mixture and beat to combine. Sift the cake flour mixture on top and continue folding until the mixture is a uniform chocolate color and no pockets of dry ingredients remain.
Scrape the batter into a 10-inch aluminum tube pan (do not butter or grease pan); if you notice any small pockets of unincorporated flour mixture, simply pause to mix them in. Gently run a thin knife through the batter in a zigzag pattern to release any large air pockets. Bake until the cake is puffed, cracked on top, and firm to the touch, about 40-45 minutes, or to an internal temperature of 206°F.
Invert the pan onto its stilts or put the opening of the center tube on a bottle so the pan is upside down. Cool upside down until absolutely no trace of warmth remains, at least 2 hours. Slide an offset spatula around the sides of the cake to loosen, lift the cake and insert out of the pan and slide a spatula under the bottom of the cake as well. Flip it onto a serving plate, lift the base and center tube gently away from the cake. To serve, cut with a large serrated knife, using a gentle sawing motion and only the slightest downward pressure.
Notes
All of the notes from the Angel Food Cake apply here as well:
Use a very large bowl - at least 6qt, 8qt if you have it available (or consider scaling the recipe down).
Wipe the whisk attachment and mixing bowl with a little bit of lemon juice to remove traces of fat.
Use a small bowl for separating each egg to avoid contaminating the larger mixing bowl if a yolk breaks
Add ingredients to the meringue gradually to avoid deflating the foam structure
Don't skip the upside down cooling step to ensure the best height for your cake
Specific to this cocoa version:
Cocoa powder contains a small amount of fat, and even that tiny bit can weaken the egg‑white protein structure. Once you add the cocoa mixture, work quickly and gently to distribute it through the meringue. Avoid trying to achieve a perfectly uniform blend — it’s better to stop early and incorporate any remaining dry pockets as you transfer the batter to the pan than to overmix and deflate your egg whites.• You can use your favorite cocoa powder for this recipe. Since there’s no chemical leavener involved, cocoa choice is almost entirely about flavor. However, if you’re using a Dutch‑processed cocoa and notice your meringue collapsing more than expected or the cake rising less than usual, try switching to a natural cocoa powder — they tend to be a bit lighter. I used Cacao Barry Extra Brute (Dutch‑processed) because I love its intense, deep chocolate flavor.